點擊圖片查看大圖■Antimony trioxide flame retardant masterbatchs, containing 70%-93% Sb2O3, with matrixes of PE, PA, PVC, PP, EVA, PS, CPE, PBT, and PC/ABS
■Deca-DBE flame retardant masterbatchs, containing 70%-80% Deca-DBE (C12OBr10), with matrixes of PE, PA, PVC, PP, EVA, PS, CPE, PBT, and PC/ABS
■DBDPE flame retardant masterbatchs, containing 70%-80% DBDPE (C14Br10H4), with matrixes of PE, PA, PVC, PP, EVA, PS, CPE, PBT, and PC/ABS
■halogen-free flame-retardants masterbatchs，with matrixes of PE, PA, PVC, PP, EVA, PS, CPE, PBT, and PC/ABS
■Red phosphorus flame retardant masterbatchs, containing 50% red phosphorus, with matrixes of PE, PA, PVC, PP, EVA, PS, CPE, PBT, and PC/ABS
■Composite flame-retardant masterbatchs
■Modified colour masterbatchs
■40+% Mg(OH)2, talc flame-retardant masterbatchs
■Smashing plastics
ATO Masterbatchs
|
Product name |
Sb2O3 Content |
Matrix resin |
Applicable products |
|
PE 90 |
90% |
LDPE |
PE and PP, injection molding or extrusion |
|
PA 80 |
80% |
PA |
PA6, PA66, injection molding |
|
EVA 90 |
90% |
EVA |
PE, PP, ABS, HIPS, injection molding or extrusion |
|
PVC 85 |
85% |
PVC |
PVC, injection molding |
|
CPE 85 |
85% |
CPE |
PE,PVC,PP,HIPS,ABS compounding |
|
PS 80 |
80% |
GPPS |
HIPS, molding |
|
ABS 80 |
80% |
ABS/SAN |
ABS, PA/ABS, PC/ABS, injection molding |
|
PBT 80 |
80% |
PBT |
PBT compound |
|
MG 80 |
80% Mg(OH)2 |
LDPE |
Cable & Wire |
|
PP 90 |
90 |
PP |
PP，injection molding or extrusion |
Comparison of Ouya Masterbatchs and Common Powders of ATO Flame Retardant
|
Ouya Granule-type FR masterbatchs |
Ouya Pellet-type FR masterbatchs |
Common ATO FR powders |
|
As the Sb2O3 particles are plastic coated, the toxicity is declined sharply. |
As the Sb2O3 particles are plastic coated, the toxicity is declined sharply. |
The product is carcinogenic and allergenic substances Micron powder, so the production of a good ventilation |
|
Due to the absence of dusts, cleaning is not needed for the processing equipments. |
Cleaning is not needed for the processing equipments. |
The dust particles contaminate easily other products, while the equipment cleaning takes a long time. |
|
Due to the surface irregularity, the granule-type products adhere easily with plastics and other additives, leading to a uniform distribution. |
Due to the higher density than the plastic matrials, the pellet-type products may sink to the bottom, leading to uneven dispersion. |
When mixed with plastic pellets, the micron-grade powders may prone to uneven distribution and stick to the mixing and conveying equipment. |
|
Antimony trioxide has been well dispersed in the masterbatch. |
Antimony trioxide has been well dispersed in the masterbatch. |
Further diversifying is need in order to achieve an desired flame retardancy |
|
Easy to realize automatic material feeding. |
Easy to realize automatic material feeding. |
In automatic process, the feeding may form "bridge" and not pause unexpectedly, causing problems to the production and product quality. |
三、Technical Data of the Typical Products
1.PE 90 Technical Data
|
Item |
Unit |
Data |
|
appearance |
White Granule/Pellet |
|
|
Granule size |
mm |
2-4 |
|
Density |
g/cm3 |
3.20 |
|
Bulk Density |
g/cm3 |
2.10 |
|
ATO content |
% |
90 |
|
ATO particle size |
micron |
0.4-1.0 |
|
Matrix materials |
Polyethylene (PE) |
|
|
Black spots |
No presence |
2. PA 80 Technical Data
|
Item |
Unit |
Data |
|
appearance |
White Granule/Pellet |
|
|
Granule size |
mm |
2-4 |
|
Density |
g/cm3 |
3.10 |
|
Bulk Density |
g/cm3 |
1.8 |
|
ATOcontent |
% |
80 |
|
ATO particle size |
micron |
0.4-1.0 |
|
Matrix materials |
Polyamide 6 (PA6) |
|
|
Black spots |
No presence |
3. EVA 90 Technical Data
|
Item |
Unit |
Data |
|
appearance |
White Granule/Pellet |
|
|
Granule size |
mm |
2-4 |
|
Density |
g/cm3 |
3.20 |
|
Bulk Density |
g/cm3 |
2.10 |
|
ATOcontent |
% |
90 |
|
ATO particle size |
micron |
0.4-1.0 |
|
Matrix materials |
Ethylene-vinyl acetate copolymer (EVA) |
|
|
Black spots |
No presence |
4. PVC 85 Technical Data
|
Item |
Unit |
Data |
|
appearance |
White Granule/Pellet |
|
|
Granule size |
mm |
2-4 |
|
Density |
g/cm3 |
3.10 |
|
Bulk Density |
g/cm3 |
1.80 |
|
ATOcontent |
% |
85 |
|
ATO particle size |
micron |
0.4-1.0 |
|
Matrix materials |
Polyvinyl chloride (PVC) |
|
|
Black spots |
No presence |
5. CPE 85 Technical Data
|
Item |
Unit |
Data |
|
appearance |
White Granule/Pellet |
|
|
Granule size |
mm |
2-4 |
|
Density |
g/cm3 |
3.10 |
|
Bulk Density |
g/cm3 |
2.00 |
|
ATOcontent |
% |
85 |
|
ATO particle size |
micron |
0.4-1.0 |
|
Matrix materials |
Chlorinated polyethylene (CPE) |
|
|
Black spots |
No presence |
6. PS 80 Technical Data
|
Item |
Unit |
Data |
|
appearance |
White Granule/Pellet |
|
|
Granule size |
mm |
2-4 |
|
Density |
g/cm3 |
2.70 |
|
Bulk Density |
g/cm3 |
1.60 |
|
ATOcontent |
% |
80 |
|
ATO particle size |
micron |
0.4-1.0 |
|
Matrix materials |
Polystyrene (PS) |
|
|
Black spots |
No presence |
7. ABS 80Technical Data
|
Item |
Unit |
Data |
|
appearance |
White Granule/Pellet |
|
|
Granule size |
mm |
2-4 |
|
Density |
g/cm3 |
2.80 |
|
Bulk Density |
g/cm3 |
1.60 |
|
ATOcontent |
% |
80 |
|
ATO particle size |
micron |
0.4-1.0 |
|
Matrix materials |
Acrylonitrile-styrene-butadiene copolymer (ABS) |
|
|
Black spots |
No presence |
8. PBT 80 Technical Data
|
Item |
Unit |
Data |
|
appearance |
White Granule/Pellet |
|
|
Granule size |
mm |
2-4 |
|
Density |
g/cm3 |
3.10 |
|
Bulk Density |
g/cm3 |
1.80 |
|
ATOcontent |
% |
80 |
|
ATO particle size |
micron |
0.4-1.0 |
|
Matrix materials |
Polybutylene terephthalate (PBT) |
|
|
Black spots |
No presence |
9. MG 80 Technical Data
|
Item |
Unit |
Data |
|
appearance |
White Granule/Pellet |
|
|
Granule size |
mm |
2-4 |
|
Density |
g/cm3 |
1.00 |
|
Bulk Density |
g/cm3 |
|
|
Mg(OH)2 content |
% |
80 |
|
Mg(OH)2 particle size |
micron |
0.4-1.0 |
|
Matrix materials |
Ethylene-vinyl acetate copolymer (EVA) |
|
|
Black spots |
No presence |
10. PP 90 Technical Data
|
Item |
Unit |
Data |
|
appearance |
White Granule/Pellet |
|
|
Granule size |
mm |
2-4 |
|
Density |
g/cm3 |
3.20 |
|
Bulk Density |
g/cm3 |
2.10 |
|
ATO content |
% |
90 |
|
ATO particle size |
micron |
0.4-1.0 |
|
Matrix materials |
Polypropylene (PP) |
|
|
Black spots |
No presence |
Typical applications
1. PE 90 Application examples
|
Performance and recipes |
ABS |
HIPS |
PPH20% Talcum powder |
PC/ABS Alloy |
|
Flame-retardant class of the final product (UL94) |
V0 @ 1.6 mm |
V0 @ 1.6 mm |
V0 @ 1.6 mm |
V0 @ 1.6 mm |
|
IZOD Notched impact strength (J/M) |
200 |
85 |
40 |
500 |
|
VICAT softening point (5kg) |
95 |
84 |
95 |
110 |
|
Melt Index (ASTM D1238) |
20-40 |
10-20 |
15-25 |
25-40 |
|
Typical formulation |
||||
|
DecaBDE/DBDPE |
14-16 |
12-14 |
18-22 |
10-13 |
|
ATO FR masterbatch PE 90 |
5-6 |
4-6 |
7-9 |
4-5 |
|
PTPE |
0.2 |
0.2 |
0 |
0.2 |
|
Other production aids |
Depending on the formulation of raw materials |
|||
2. PA 80 Application examples
|
Performance and recipes |
PA6 |
PA6 GF30 |
PA66 |
PA66 GF30 |
|
Flame-retardant properties (UL94) |
V0 @ 1.6 mm |
V0 @ 1.6 mm |
V0 @ 1.6 mm |
V0 @ 1.6 mm |
|
PDBS-80 U.S. Great Lakes |
20-25 |
23-24 |
20-25 |
23-24 |
|
ATO FR masterbatch PA80 |
10-12 |
9-10 |
10-12 |
9-10 |
|
Other production aids |
Depending on the formulation of raw materials |
|||
3. PVC 85 Application examples
|
Performance and recipes |
PVC (DOP 60 phr) |
PVC (DOP 40 phr) |
|
Flame-retardant properties（Limited Oxygen index, LOI） |
27 |
31 |
|
ATO FR masterbatch PVC85 |
6 phr |
6 phr |
|
Other production aids |
Depending on the formulation of raw materials |
|
Other representative of flame-retardant masterbatchs
PE 90 Granule Halogen-freePAEPFR-200A PE.DBDPE80 PA Red phosphorus 50
UM300A Halogen-free EMA-MC Halogen-free PP 200A Halogen-free PA6-EPFR Halogen-free
PE105 DBDPE +Sb2O3 DBDPE UN85 EVA80 ABS Modified
PA6-80 Particle UN406
Colour Masterbatchs:
■General Colour masterbatchs used for: polyethylene, polypropylene, ABS , HIPS, PS, nylon, PET, polypropylene spinning, PE cable protective sleeve, communication cable, PE foams, PS foams.
■Black colour masterbatchs dedicated for pipes: PE water supplying pipe, large diameter PE pipe, double wall corrugated pipe, pipe-linemarking, PP-R pipe, carbon pipe, threading pipe, pipe jacket.
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